The design and synthesis of metal-carboxylate coordination polymers
نویسندگان
چکیده
منابع مشابه
Coordination polymers and metal-organic frameworks: materials by design.
The field of coordination polymers and metal–organic frameworks (MOFs) has evolved over a period of approximately 25 years to a stage where it is one of the most widely investigated areas of materials chemistry. The field has impacted many areas of science including commercial applications from gas storage agents to new investigations as drug-delivery vehicles [1]. Coordination polymers and MOF...
متن کاملMetal-carboxylate coordination polymers with redox-active moiety of tetrathiafulvalene (TTF).
Though numerous metal-organic frameworks or polymers have been reported, the organic building blocks are usually not redox-active. On the other hand, some mono-, di- or tri-nuclear compounds with tetrathiafulvalene (TTF) have been prepared, although little is known about the coordination polymers combined with paramagnetic metals and organic TTF ligands. We report herein a series of coordinatio...
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Chemical sensors for rapid detection of explosives are important for the versatile applications in security screening, industrial process control, and environment monitoring. Many explosive compounds possess electron withdrawing nitroaromatic groups, and often act as good electron acceptors. Electron donor conjugated polymers have been seen as one of the most promising candidates for detection ...
متن کاملFluorescent nanoscale zinc(II)-carboxylate coordination polymers for explosive sensing.
Fluorescent nanoscale coordination polymers with cubic morphology and long range ordered structure were fabricated and exhibited efficient sensing for both nitroaromatic explosive and nitromethane due to large surface area to volume ratio and strong binding affinity to explosive molecules.
متن کاملSonochemical Synthesis of two New Nano-structured Lead(II) and Mercury(II) Coordination Polymers
Two new nano-sized lead(II) and mercury(II) coordination polymers, [Pb(2-bpdh)(NO3)2(H2O)]n(1); (2-bpdh = 2,5-bis(2-pyridyl)-3,4-diaza- 2,4-hexadiene)} and [Hg(4-bpdb)(SCN)2]n (2); (4-bpdb= 1,4-bis(4- pyridyl)-3,4-diaza-1,3-butadiene) were synthesized by a sonochemical method. The structure of 1 may be considered coordination polymer of lead(II) and Single crystal X–ray analysis of compound ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2006
ISSN: 0108-7673
DOI: 10.1107/s0108767306094384